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MSDS Silicone Softener LS06
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SAFETY DATA SHEET

 Silicone Softener LS06

SECTION 1. Identification of Substance and Company

 

Product  : Silicone Softener LS06

Company Zhejiang Liansheng New Material Co., Ltd.

Address  : Haixia Road No. 68, Xitangqiao Street, Haiyan, Jiaxing city, Zhejiang, China.    

Post Code: 314300      

Emergency Tel: 86-512-65907588      Fax86-512-65901660

Websitewww.lshx.cn


SECTION 2.  Hazards Identification


Classification of the substance      :  LONG-TERM AQUATIC HAZARD - Category 3

 or mixture GHS label elements

Signal word                       :  No signal word.

Hazard statements                   : H412 - Toxic to aquatic life with long lasting effects

Precautionary statements

Prevention                          : P273 - Avoid release to the environment

Response                            : P391 - Collect spillage.

Storage                                            : Store in accordance with all local, regional, national and

 international regulations.

Disposal                                         : P501 - Dispose of contents and container in accordance

with all local, regional, national and International

regulations.


Symbol                        :


Other hazards which do not       :  None known.

result in classification


SECTION 3. Main Composition/Property

Main Composition:polysiloxane elastomer

Appearance :  bluish semi-transparent liquid

Main Function:it is suitable for the hydrophilic and soft finishing of cotton, cotton blended fabric and cotton towel.

      

SECTION 4.   First aid measures

Description of necessary first aid measures

Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.

            If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial

respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to

give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or

are severe. If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of

inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person

may need to be kept under medical surveillance for 48 hours.

Ingestion :  Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and

keep at rest in aposition comfortable for breathing. If material has been swallowed

 and the exposed person is conscious, give small quantities of water to drink. Stop if

the exposed person feels sick as vomiting may be dangerous. Do notinduce vomiting

unless directed to do so by medical personnel. If vomiting occurs, the head should be

 kept low so that vomit does not enter the lungs. Get medical attention if adverse

 health effects persist or are severe. Never give anything by mouth to an unconscious

 person. If unconscious, place in recovery position and get medical attention

immediately. Maintain an open airway. Loosen tight clothing such as a collar,

 tie, belt or waistband.

Skin contact:  Flush contaminated skin with plenty of water. Remove contaminated clothing

 and shoes. Get medical attention if symptoms occur. Wash clothing before reuse.

Clean shoes thoroughly before reuse.


Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower

 eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.

 Get medical attention if irritation occurs.

Most important symptoms/effects, acute and delayed Potential acute health effects

Inhalation :   No known significant effects or critical hazards.

Ingestion :    There may be irritation of the throat.

Skin contact :  May be mild irritation at the site of contact.

Eye contact :  There may be irritation and redness.



SECTION 5. Flammability & explosibility and fire fighting measures

Extinguishing media

Suitable : Use an extinguishing agent suitable for the surrounding fire

Not suitable : None known

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst

 from the chemical     This material is toxic to aquatic life with long lasting effects. Fire water  

                        contaminated with this material must be contained and prevented from being

                   discharged to any waterway, sewer or drain.

Hazardous thermal :    Decomposition products may include the following materials:

decomposition products  carbon dioxide; carbon monoxide ; nitrogen oxides

Special precautions for  Promptly isolate the scene by removing all persons from the vicinity of the

 fire- fighters:           incident if there is a fire. No action shall be taken involving any personal

                     risk or without suitable training.

Remark :  Not  available.

 

 

SECTION 6  Leakage Emergency Measures


Emergency measures:

Personal protection: keep away from eyes and wear protective articles.

Environment protection : limit entry of nonproduction workers and collect and put leakage material in

sealed container, rinse the spot and discharge waste water  into specified water

treatment system.


SECTION 7   Handle and storage

Handle

          Take care of load and unload in order to avoid sprinkle due to package breakage. easily agglomerate exposed to the moisture, it’s unadvisable to handle them when raining, unless under rain shelter.

Storage

           Can be storged one year in cool and well-ventilated warehouse, avoid insolation, seal the drum immediately after use, the shelf life is 6 monthes.


         

SECTION 8  Protection Measures

Appropriate engineering

controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants


Environmental exposure

 controls :     Emissions from ventilation or work process equipment should be checked to ensure

             they comply with the requirements of environmental protection legislation. In some

            cases, fume scrubbers, filters or engineering modifications to the process

             equipment will be necessary to reduce emissions to acceptable levels.

Engineer Control: keep workshop and storage room ventilated and materials sealed.

Operation Protection: keep materials away from eyes and ventilate during production and usage. Thoroughly rinse after operation.

Personal Protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard

should be worn at all times when handling chemical products if a risk

assessment indicates this is necessary. Use gloves approved to relevant standards e.g.

EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on

usage, e.g. frequency and duration of contact, chemical resistance of glove material

 and dexterity. Always seek advice from glove suppliers.

Eye protection :  Safety eyewear complying with an approved standard should be used when a risk

                 assessment indicates this is necessary to avoid exposure to liquid splashes, mists,

               gases or dusts. If contact is possible, the following protection should be worn,

               unless the assessment indicates a higher degree of protection: safety glasses with

              side-shields.

Skin protection : Personal protective equipment for the body should be selected based on the task

                 being performed and the risks involved and should be approved by a specialist

                 before handling this product.


 

SECTION 9.   Physical and chemical Properties

 

Appearance:semi-transparent liquid

Color:bluish

Odor : slight odor

Ionicity: cationic

pH :  4.5-6.0 (1% aqueous solution)     

Solublity can completely dissolved by room water.

Flammability (solid, gas) :  Not  available.

Vapour pressure : Not  available.

    

SECTION 10.   Stability and Reactivity


Chemical stability: stable under in cool and well ventilated conditons.

Possibility of hazardous : Under normal conditions of storage and use,  hazardous reactions

Reactions              will not occur  

Conditions to be avoided: No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition

Products                products should not be produced.

 

SECTION 11.  Toxicological Information

Information on the likely routes of exposure

Inhalation :   No known significant effects or critical hazards.

Ingestion :     There may be irritation of the throat.

Skin contact :  May be mild irritation at the site of contact.

Eye contact :  There may be irritation and redness.

Acute Toxicity : LD50  /( rat) >2000mg/kg    


SECTION 12.   Ecological Information

Environmental effects : Not readily biodegradable, water polluting material.May be harmful to the

                     environment if released in large quantities. This material is toxic to aquatic

                     life with long lasting effects.

Aquatic and terrestrial toxicity(LC50): No data available

Ecological DegradationNo data available

Mobility : No data available

BOD  : No data available

COD  : No data available

Metal Content : Metal content under the ETAD recommended limits.

Other adverse effects :No known significant effects or critical hazards.


SECTION 13.   Disposal consideration

 

Disposal methods: The generation of waste should be avoided or minimised  wherever possible.Disposal of

this product,solutions and any by-products should at all times comply with the

requirements of environmental protection and waste disposal legislation and any regional

local authority requirements. Waste can’t discharged into sewer and any water area or on

ground unless fully compliant with the requirements of all authorities with jurisdiction.

This material and its container must be disposedof in a safe way.


SECTION 14.   Transport Information

International transport regulations

14.1-14.4 UN number; UN proper shipping name; Transport hazard class(es); Packing group

Road ADR:

Valuation  : Not regulated for transport

Railway RID :

Valuation  :Not regulated for transport

Transport by sea IMDG-Code:

Valuation  :Not regulated for transport

14.5 Environmental hazards

Hazardous to the environment: no

14.6 Special precautions for user

Relevant information in other sections have to be considered

14.7 Transport in bulk according to Annex of MARPOL73/78 and IBC Code

Bulk transport in tankers is not intended.


SECTION 15.   National and International Regulations


15.1 Safety,health and environmental regulations/legislation specific for the substance or mixture

    National and local regulations must be observed.

15.2 Other international regulations

Details of international registration status:

Listed on or in accordance with the following inventories:

EINECS- Europe                                       

SECTION 16.   Other Information

Reference Literature

New Regulations for Chemicals Safety Management Yu Zhiming  Chief Editor  Chemical Industry Press 2001;

Safety Management for chemicals on working area  Shan Chunchang Chief Editor  Chemical Industry Press 2000;

Work handbook for Chemicals safety original Labour Safety Bureau of Chemicals Industry

Filled on: Jan. 1st, 2024

Filled by:Tech. Dept of Textile chemicals Zhejiang Liansheng New Material Co., Ltd.

Check Unit  Zhejiang Liansheng New Material Co., Ltd.

Edit       based on existing materials

Version        the third 2024

This information is based on our present knowledge and certainly correct and latest. However it shall not consitite commitment and responsibility for any specific products. Only as instruction as be used by clients, it shall not establish a legally valid contractual relationship.